Browsing by Author "Gazi, Mustafa"
Chelate extraction of transition metal ions by ethylene diamine diacetic acid with n-substituted octadecyl groups Authors:Bıçak, Niyazi; Şungur, Şana Kutun; Tan, Nükhet; Gazi, Mustafa
Publisher and Date:(Taylor & Francis Inc, 2002)An organic-soluble chelating agent NN'-di-n-octadecyl ethylenediamine-NN'-diacetic acid (DOED) has been synthesized in two steps by (i) condensation of dibromoethane with 1-amino octadecane (octadecylamine) and (ii) subsequent reaction with sodium chloro acetate in alcohol-water mixture. The chelating agent in 2-ethylhexanol-cyclohexanol (1:1) solutions shows extremely high chelating ability for Ni(II) Co(II) Cu(II) Fe(111) Cr(III) and Cd(II) ions in neutral aqueous solutions. Extractions take ...
Authors:Bıçak, Niyazi; Sungur, Sana; Gazi, Mustafa; Tan, Nükhet
Publisher and Date:(Marcel Dekker Inc, 2003)N-octyl methane sulfonamide (OMSA) has been demonstrated to be a very efficient reagent for selective extraction of Hg(II) ions from aqueous solutions. The extraction bases on rapid reaction of OMSA with Hg(II) ions yielding mono and disulfonamido mercury compounds in ordinary conditions. Solubility of OMSA and its mercury compounds in 2-ethyl hexanol provide a clear-cut phase separation in the extraction. The solution of OMSA in 2-ethyl hexanol (0.4 mol L-1) is able to extract 82.2% of mercuric-acetate ...